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two.2]decane core and defining the geometry of your exocyclic double bond. The activation energies of formation on the vinyl-gold intermediates have been calculated and revealed a silyl enol ether with an unprotected indole moiety as an appropriate precursor for the Toste cyclization. This 6-act

two.two]decane core and defining the geometry on the exocyclic double bond. The activation energies of development from the vinyl-gold intermediates ended up calculated and unveiled a silyl enol ether with an unprotected indole moiety as an acceptable precursor for that Toste cyclization. This s